Picked up a 15lb bag of Florida crushed coral and just finished loading about 3/4 of a basket with it. Still have a bunch left so would it help at all just mixing some in to the substrate as well, or does it not do any good at all if its not in front of moving water?
If you've ever dissolved sugar in hot water, here's an analogy. If you drop in a lump of sugar, but don't stir it, it'll dissolve slowly. If you stir it, it'll dissolve quicker.

If you add it to the substrate, it will help some, but perhaps not as much. Then again it's not like you want the coral to dissapear quickly or you'll just have to keep buying more.

If you think it'll look good mixed into the substrate, then go for it! Otherwise, I don't think it's necessary. If you do mix it in and decide you wish you hadn't, it'll probably be a chore to get it back out.